Infrared Spectroscopy of Symmetric and Spherical Top Molecules for Space Observation, Volume 2. Pierre-Richard DahooЧитать онлайн книгу.
spectra of diatomic molecules (homonuclear or heteronuclear), triatomic molecules (linear or nonlinear, symmetric or non-symmetric) in the gas phase and particularly when they are trapped in the nanocages of inert matrices of rare gases, or hydrate clathrates at a very low temperature. Volume 3 deals with the spectroscopy of symmetric and spherical tops in the gas phase.
This book (Volume 4) is a continuation of Volume 3, focusing on the application of theoretical models for the simulation of IR spectra of symmetric or spherical top species evolving in various media. The method of an extended substitution model is explained in terms of the determination of the type of symmetry of the environment in the immediate vicinity of the trapped molecule. The objective is to propose theoretical spectra that match with experimental IR data and hence identify molecules based on transitions and profiles, not only in the gas phase, but also when they are constrained to evolve in an environment, such as a nanocage or a surface.
Chapter 1 provides a brief overview of the instruments developed and used in the laboratory for the study or observation of molecules, FTIR spectroscopy or laser cavity spectroscopy. An example of embedded instruments such as SPICAM, SPICAV or SOIR aboard an orbiter or a space probe serves to illustrate the instrumental context of space observation and of the international collaboration required to develop measurement instruments, as well as the analysis methods for the identification according to the scientific norms of the molecules that may be present in the probed atmosphere, such as on Mars or Venus during Mars Express and Venus Express missions. Aerosol characterization by spectroscopic ellipsometry is also discussed as a non-standard method. The LIDAR technique, which is used for observing the terrestrial atmosphere, is also described.
Chapter 2 presents various contributions to the interaction potential energy between the studied molecule and its solid environment, considering the hypothesis of binary interactions: “studied molecule – molecule or atom of the environment”. The quantum “dispersion–repulsion” contribution is modeled by an atom–atom Lennard-Jones potential energy type, while the electrical contribution is modeled by a charge–charge potential energy in the case of clathrate nanocages or multipole–multipole in the case of nanocages of rare gas, fullerene or graphite substrate matrix.
Chapter 3 provides a description of the substitution model applied to the study of NH3 in rare gas matrices. An atom–atom potential is used to calculate the interaction between the trapped molecule and its environment. A numerical method is applied to determine the perturbed motions of the molecule. The IR spectral profiles are determined and compared to the experimental spectra. The influence of lattice phonon modes on the shift and width of spectral lines is also discussed.
Chapters 4 and 5 provide a description of the extended substitution model, based on the effect of the local symmetry around the equilibrium position of the molecule in the cage for calculating IR spectra in natural nanocages, such as clathrates and fullerene. This model relies on the substitution model used for building theoretical models in IR spectroscopy in rare gas matrices. The model is applied to CH4 and NH3 molecules included in clathrate nanocages (Chapter 4) and NH3 in a fullerene nanocage.
In Chapter 6, the theoretical models developed in Volumes 1 and 2 to deal with the adsorption of diatomic and triatomic molecules on a graphite substrate, are applied to the NH3 molecule in order to determine the IR absorption spectra at a very low temperature. This substrate is often used to model the surface of interstellar dust grains.
Pierre Richard DAHOO
Azzedine LAKHLIFI
June 2021
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