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1.1 Simple description of 3D MOF chemistry [1].Figure 1.2 Some examples of metal nodes, organic linkers, and MOFs (definition o...Figure 1.2 (Continued) Some examples of metal nodes, organic linkers, and MOFs (...Figure 1.2 (Continued) Some examples of metal nodes, organic linkers, and MOFs (...Figure 1.3 Some examples of MOFs synthesis methods.

2 Chapter 2Figure 2.1 Simple language to understand concept of complexity [45].Figure 2.2 Overview of this book based on the effective factors in the construct...Figure 2.3 Classification of complexity key factors in MOFs (further details in ...Figure 2.4 A cost-effective mixed-metal mixed-ligand MOF, which exhibits highly ...Scheme 2.1 The conversion of an achiral MOF to a chiral MOF by using an achiral ...Figure 2.5 Defective linker concept for defect-engineered MOFs [44].

3 Chapter 3Figure 3.1 A photocatalyst MOF with three different ditopic linkers [9].Figure 3.2 Structural analyses of a MOF-based photocatalyst with three different...Scheme 3.1 Structure of the used ligands.Figure 3.3 (a) Copper-phosphonate CBU polyhedral. Octahedral Cu1 and square pyra...Figure 3.4 Schematic representations of the happened processes in MOF with incre...Figure 3.4 (Continued) Schematic representations of the happened processes in MO...Figure 3.5 Schematic representations of construction mechanism. (a) Formed micro...Figure 3.5 (Continued) Schematic representations of construction mechanism.(a) F...Figure 3.6 One kind of mixed-valence Ru^II/III MOF with mixed-linker [23].Figure 3.7 Olefin hydrogenation mechanism [23].Figure 3.8 Zeolite-like MOFs based on mixed linkers [43].Figure 3.9 A mixed-ligand MOF with two ligands BTC (benzene-1,3,5-tricarboxylate...Figure 3.10 Stepwise preparation of {[Cu₄(CDC)₄(4,4′-bipy)(H₂O)₂]₃}_n·xS. Copper:...Figure 3.11 ADES-1: (a) coordination environment around Zn(II); (b) and (c) [Zn₂...Figure 3.12 ADES-2: (a) coordination environment around Cd(II); (b) and (c) [Cd₂...Scheme 3.2 Structures of the used organic dyes.Scheme 3.3 Biginelli reaction by using ADES-1.Figure 3.13 Direct synthesis of mixed-ligands MOF film, RuB-RuTB-UiO-67/TiO₂/FTO...

4 Chapter 4Figure 4.1 Some of the tritopic linkers.Figure 4.2 The symmetry in organic linker. Tetratopic linkers with (a) symmetry ...Figure 4.3 Some of the tetratopic linkers.Figure 4.4 A mixed-ligand MOF with tetratopic organic linkers [10].Figure 4.5 Some of the multi-topic linkers.Figure 4.6 A kind of MOF with multi-hetero topic organic linker [4].Figure 4.7 (a) Cu(II) Coordination environment. Symmetric nodes: (i) y, 1 - x, 1...

5 Chapter 5Figure 5.1 Two synthesis strategies to create MM′-MOFs.Figure 5.2 Two synthetic methods to create 2D gird MM′-MOFs [36].Figure 5.3 The incorporated BPDC, RuDCBPY, and PtDCBPY into Zr-MOF (UiO-67) thro...Figure 5.4 (a) Powder x-ray diffraction patterns, (b) IR spectra, and (c) TGA an...Figure 5.5 (a–c) SEM and (d–j) HAADF-STEM images of the considered samples (top)...Figure 5.6 The formation of coordination polymers from the corresponding metals ...Figure 5.7 The epitaxial growth of the trimetallic and bimetallic hetero-(Ln)-MO...Figure 5.8 Transmetalation in porph@MOM-10 (a) and MSO-MOF (b). [Panel (b): meta...Figure 5.9 (a) 3D structure of [Gd₃Cu₁₂I₁₂(IN)₉(DMF)₄]_n.nDMF. (structure I) (b) ...Figure 5.10 The solid-state luminescent properties of MOFs with diverse SBUs [58...Figure 5.11 (a and b) MOF 1 structure showing Co₃ SBU supported by Co1 and Co2 v...

6 Chapter 6Figure 6.1 (a) Two types of chiral tetrahedral SBUs. (b) A perspective view of m...Figure 6.2 (a) Schematic representation of a chiral MOF catalyst by PSM. (b) The...Figure 6.3 Crystal structure of chiral MOF-1a. (a) Paddle-wheels clusters based ...Figure 6.3 (Continued) Crystal structure of chiral MOF-1a. (a) Paddle-wheels clu...Scheme 6.1 Synthesis conditions to produce chiral metal-camphorate coordination ...Scheme 6.2 Coordination modes of D-Cam and D-HCam in polymeric structures 1–5.Figure 6.4 (a and b) Views of connectivity around metallic centers in structure ...Figure 6.5 Total synthesis of CMOF with chiral axial ligand [59].Figure 6.6 Different cavity sizes in CMOFs [58].Figure 6.7 Stick/polyhedra models of CMOF-1-5 with the presence of interpenetrat...

7 Chapter 7Figure 7.1 An example of the chiral templating effect origin [1].Figure 7.2 Synthesis method of Ni-PYI1, guest exchange, and the considered asymm...Figure 7.3 Examples of the post-chiral modification of achiral MOF-NH₂ as capill...Figure 7.4 (a–d) GC chromatograms based on chiral MOF-based columns to separate ...Figure 7.5 The example of modified MOF with chiral species through postchiral mo...Figure 7.6 Asymmetry unit in Zn-DPYI crystal structure (left). Crystal structure...Scheme 7.1 Synthesis method of chiral [MIL-101(Cr)-tart].Figure 7.7 The preparation steps of one kind of chiral Zn-MOF through post-synth...Scheme 7.2 Interactions in the preparation of [MIL-101(Cr)-tart].Scheme 7.3 The preparation steps of post-chiral modification NU-1000 by SALI met...

8 Chapter 8Figure 8.1 A plot based on the number of published articles about the defect of ...Figure 8.2 MOF with interpenetration [76].Figure 8.3 Different cases of MOFs with various mixed linkers. (a) The parent MO...Figure 8.4 MIL to different forms: (a) without any defect, (b) dangling organic ...Figure 8.5 Defective UiO-66(Zr)-(OH)₂ framework for CO₂ capture [82].

9 Chapter 9Figure 9.1 (a) H₄PANAD structure. (b) HHU-1 network with varying size pores (two...Figure 9.2 Heterogeneous pores due to missing node or ligand [28, 29].Figure 9.3 An example of MOF-based porous carbon (NHOPC) with multiporosity synt...Figure 9.4 Examples of Cr-MILs as mesoMOFs with two types of mesocages [43, 44].

10 Chapter 10Figure 10.1 Schematic representation of bio-MOF composite [21].Figure 10.2 Heteroepitaxially grown hybrid IRMOF-3@1 and structures of IRMOF-1 a...Figure 10.3 Optical micrographs: (a) hybrid IRMOF-3@1, (b) IRMOF-1@3. (IRMOF-1: ...Scheme 10.1 Suggested mechanism of carbon dioxide cycloaddition with epoxide by ...Figure 10.4 Isostructural Eu/Tb mixed MOFs with different triplet energy levels ...