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Mathematics for Enzyme Reaction Kinetics and Reactor Performance. F. Xavier MalcataЧитать онлайн книгу.

Mathematics for Enzyme Reaction Kinetics and Reactor Performance - F. Xavier Malcata


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      once n + 1 has been factored out – which retrieves Eq. (2.83) pertaining to a plain arithmetic series, as expected. This conclusion can also be drawn graphically, by comparing the curves labeled as k2 = 1 in Fig. 2.6 with the lines in Fig. 2.4 corresponding to the same images; and goes along with realization that

      (2.133)equation

      based on Eq. (2.110) and matching Eq. (2.76).

      A polynomial in x refers to a sum of powers of integer exponent on x; such algebraic functions are accordingly the easiest in terms of calculation – including numerical methods, as they basically involve just multiplications and additions. In principle, any continuous function of practical interest may be expressed via a polynomial (as will be derived later); hence, algebraic operations involving polynomials are of the utmost interest for process engineering. Besides the trivial operation of addition – where terms with identical exponents of x are merely lumped, i.e.

      (2.134)equation

      and

      multiplication and division of polynomials appear as germane. An iterated version of the former entails the power of a polynomial, whereas the iterated version of the latter supports factorization of a polynomial – i.e. conversion from a sum to a product of simpler (usually linear) polynomials.

      2.2.1 Product

      (2.137)equation

      upon application of the distributive property of multiplication, one obtains

      (2.138)equation

      or else

      2.2.2 Quotient

      With regard to division of a dividend polynomial, say, Pn {x}, by a divisor polynomial, say, Pm {x}, one will eventually be led to

      on account again of Eqs. (2.135) and (2.136) – provided that n ≥ m; here Qn−m denotes an (n – m)th degree quotient polynomial, and R<m denotes a remainder polynomial of degree not exceeding m. The underlying algorithm is but an extension of Euclidean (long) division algorithm for regular numbers; one should thus start by dividing the highest order term, an xn, of the dividend polynomial by the highest order term, bm xm, of the divisor polynomial – so an xn−m /bm always appears as first term of the quotient polynomial; multiplication should then proceed of said quotient term by every term of the divisor – followed by subtraction of the result from the dividend. In other words, the first step of division should lead to

      (2.142)equation

      which simplifies to

      (2.144)equation

      that degenerates to

      (2.145)equation

      after lumping the coefficients of similar powers of x – and the process may be iterated for the third term, the fourth term, and so on. The above algorithm is thus to be repeated until the degree of the polynomial in numerator of the last term is lower than its denominator counterpart; it may even reduce to zero – in which case Pn


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