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Mathematics for Enzyme Reaction Kinetics and Reactor Performance. F. Xavier MalcataЧитать онлайн книгу.

Mathematics for Enzyme Reaction Kinetics and Reactor Performance - F. Xavier Malcata


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      Equation (2.236) obviously applies when a difference rather than a sum is at stake – as already perceived with Eq. (2.238); just replace y by −y, and then apply Newton’s binomial formula to x and −y, according to

      – where the minus sign is often taken out to yield

      (2.264)equation

      at the expense of (1)k = (1)−k .

      As mentioned previously, Newton generalized the binomial theorem so as to encompass real exponents other than nonnegative integers – and eventually came forward with

      where the generalized (binomial) coefficient should then read

      (2.266)equation

      en lieu of Eq. (2.240); Pochhammer’s symbol, ((r))k, stands here for a falling factorial, i.e.

      with ((r))0 set equal to unity by convention – which, if r > k − 1 is an integer, may be reformulated to

      (2.268)equation

      (2.270)equation

      (2.271)equation

      following straightforward algebraic manipulation and condensation afterward. If r is instead set equal to 1 and y set equal to 1, then Eq. (2.265) gives rise to

      (2.272)equation

      – where algebraic rearrangement supports dramatic simplification to

      (2.273)equation

      the right‐hand side is but a geometric series of first term equal to 1 and ratio between consecutive terms equal to −x, so one may retrieve Eq. (2.93) to write

      (2.274)equation

      since images when ∣x ∣ < 1 – also consistent with (x + 1)−1 representing the reciprocal of x + 1 in the first place, as obtained by long division of 1 by 1 + x following the algorithm depicted in Fig. 2.8. One also finds that

      If a rising factorial, (z)k, is defined as

      (2.277)equation

      (2.278)equation

      In the case of a trinomial, its square may be calculated via

      (2.279)equation

      in agreement with Eq. (2.237) applied to x1 + x2 and x3, rather than x and y; a second application of said formula to (x1 + x2)2 generates

      (2.280)equation

      that may be rearranged to read

      upon elimination of parenthesis. The above reasoning may be applied to any (integer) exponent n, and to any number m of terms of polynomial x1


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