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Mathematics for Enzyme Reaction Kinetics and Reactor Performance. F. Xavier MalcataЧитать онлайн книгу.

Mathematics for Enzyme Reaction Kinetics and Reactor Performance - F. Xavier Malcata


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      with a scalar quantity being now at stake.

      Being an array of numbers, arranged as m rows × n columns, and enclosed by a set of square parenthesis, [ai,j] with i=1,2,…,m and j=1,2,…,n, a real matrix actually originates from Rm×n . It is termed rectangular when mn, and square when m=n; and reduces to a row vector when m = 1, or a column vector when n = 1. The main diagonal is formed by elements of the type ai,i; if all entries below the main diagonal are zero, the matrix is said to be upper triangular and lower triangular when all entries above the main diagonal are nil. A diagonal matrix is both upper and lower triangular, i.e. all elements off the main diagonal are zero; if all elements in the diagonal are, in turn, equal to each other, then a scalar matrix arises. The most important scalar matrices are square (m × m) identity matrices, containing only 1’s in the main diagonal, and denoted as Im . A nil matrix is formed only by zeros, and is usually denoted as 0m×n .

      When elements symmetrically placed relative to the diagonal are the same, the matrix is termed symmetric; all diagonal matrices are obviously symmetric. The sum of the elements in the main diagonal of matrix A is denoted as trace, abbreviated to tr A . When rows and columns of matrix A with generic element ai,j are exchanged – with elements retaining their relative location within each row and each column, its transpose AT results; it is accordingly described by [aj,i]. Finally, the requirement for equality of two matrices is their sharing the same type (i.e. identical number of rows and identical number of columns) and the same spread (i.e. identical numbers in homologous positions).

      Consider a generic (m × n) matrix A, defined as

      – or via its generic element (and thus in a more condensed form)

      where subscripti refers to ith row and subscriptj refers to jth column; if another matrix, B, also of type (m × n), is defined as

      then A and B can be added according to the algorithm

      – so the sum will again be a matrix of (m × n) type.

      Addition of matrices is commutative; in fact,

      may be handled as

      (4.7)equation

      If a third matrix C is defined as

      then one can write

      (4.10)equation

      together with Eqs. (4.2) and (4.3); based on Eq. (4.4), one has that

      (4.11)equation

      – along with the associative property borne by addition of scalars. One may repeat the above reasoning by first associating A and B, viz.

      (4.13)equation

      (4.14)Скачать книгу

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