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Mathematics for Enzyme Reaction Kinetics and Reactor Performance. F. Xavier MalcataЧитать онлайн книгу.

Mathematics for Enzyme Reaction Kinetics and Reactor Performance - F. Xavier Malcata


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(4.95), so one readily concludes that

      (4.99)equation

      – whereas combination with Eq. (4.57) leads finally to

      Remember that BC is an (n × m) matrix and A is an (m × n) matrix, so ( BC) A = BCA is an (n × n) matrix – and thus distinct from the (m × m) matrix ( AB) C = ABC as outlined above, due to the product of matrices not being commutative; nevertheless, the traces of BCA and ABC are the same. A similar derivation would prove that

      (4.101)equation

      A particular situation covered by Eq. (4.100) pertains to an (n × m) matrix A and an (m × n) matrix C, together with Im playing the role of matrix B; the products ABC and BCA in Eq. (4.100) look like

      (4.102)equation

      which degenerates to

      (4.103)equation

      at the expense of Eqs. (4.61) and (4.64). Therefore, the trace of the product of two matrices remains unchanged when the said matrices switch positions (should that be compatible with multiplication).

      Recall again matrix A, as defined by Eqs. (4.1) and (4.2); if generic element ai,j, initially located in the ith row and jth column, were swapped with element aj,i, initially located in the jth row and ith column, then a transpose matrix would result – given by

      so AT will be an (n × m) matrix. The order of a square matrix is obviously not changed upon transposal – neither do the diagonal elements (characterized by i = j), irrespective of its order; hence, one finds that

      (4.106)equation

      for a square A . Furthermore, if the elements symmetrically located with regard to the main diagonal are identical, then

      a matrix bearing this property is termed symmetric – a concept distinct from that conveyed by Eq. (4.44) that involves two matrices. A particular case of the above statement is the identity matrix – since ai,j≠i = 0 = aj,i; hence,

      (4.109)equation

      which may be condensed to

      therefore, the inverse of transposal coincides with transposal itself, as composition of the two leaves the original matrix unchanged.

      When transposal is combined with addition of matrices, one obtains

      (4.111)equation

      from Eqs. (4.2) and (4.3), after direct combination with Eq. (4.105); whereas the algorithm conveyed by Eq. (4.4) gives rise to

      which is equivalent to

      given


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