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href="#ulink_68b4b640-4bfb-56e1-95c8-69f3dbea2e80">9.7 Conclusion References

13 10 Directing Group Assisted Distal C(sp³)–H Functionalization of Aliphatic Substrates 10.1 Introduction 10.2 γ‐C(sp3)–H Functionalization of Aliphatic Acids 10.3 δ‐/ɛ‐C(sp3)

H Bond Functionalization of Aliphatic Amines 10.4 γ‐C(sp3)

H Bond Functionalization of Aliphatic Ketones or Aldehydes 10.5 γ‐/δ‐C(sp3)

H Bond Functionalization of Aliphatic Alcohols 10.6 Conclusions and Outlook References

14 11 Radically Initiated Distal C(sp³)–H Functionalization 11.1 Introduction 11.2 Distal C(sp3)–H Functionalization Promoted by Carbon‐Centered Radicals 11.3 Distal C(sp³)–H Functionalization Promoted by Nitrogen‐Centered Radicals 11.4 Oxygen‐Centered Radicals Initiate Distal C(sp3)–H Functionalization 11.5 Summary and Outlook References

15 12 Non‐Directed Functionalization of Distal C(sp³)

H Bonds 12.1 Introduction 12.2 Reactions Occurring Without Formation of Metal–Carbon Bonds 12.3 Reactions Occurring via Formation of Metal–Carbon Bonds 12.4 Altering Innate Reactivity by Polarity Reversal Strategies Acknowledgments References

16 13 Remote Oxidation of Aliphatic C

H Bonds with Biologically Inspired Catalysts 13.1 Introduction 13.2 Innate Substrate Based Aspects Governing Site Selectivity in C–H Oxidations 13.3 Remote Oxidations by Reversal of Polarity 13.4 Remote Oxidations Guided by Supramolecular Recognition 13.5 Selective Aliphatic C–H Oxidation at Dicopper Complexes 13.6 Conclusions References

17 Index

18 End User License Agreement

List of Tables

1 Chapter 3Table 3.1 Bisfunctionalization of aryl (pseudo)halides under Pd(0)/NBE cataly...

2 Chapter 12Table 12.1 Examples of BDEs of aliphatic C

H bonds [5].

3 Chapter 13Table 13.1 Catalyst dependent selective oxidation of the androstanediol deriv...Table 13.2 C9 hydroxylation of the androstanediol derivativeS2 _R.Table 13.3 Oxidation of ibuprofen with theMn ₂ (terpy–COOH) catalyst.Table 13.4 Evidence on favor of a recognition‐driven selectivity.

List of Illustrations

1 Chapter 2Scheme 2.1 Directing template assisted meta‐C

H bond functionalization. Rela...Scheme 2.2 Three categories of chelating functionality (CF). (a) N‐Based...Scheme 2.3 meta‐C–H activation of toluene derivatives.Scheme 2.4 meta‐C–H olefination of hydrocinnamic acid derivatives. Scheme 2.5 (a) 2‐hydroxybenzonitrile template assisted mono meta‐selective o...Scheme 2.6 (a) Proposed remote‐selective C‐H activation via κ2 coordination ...Scheme 2.7 (a) Rh(III)‐catalyzed directing template assisted remote meta‐C–H...Scheme 2.8 meta‐C–H arylation of hydrocinnamic acids with arylboronic ...Scheme 2.9 meta‐C–H arylation of hydrocinnamic acids with aryl iodides...Scheme 2.10 meta‐C–H olefination of phenylacetate.Scheme 2.11 meta‐C–H olefination of phenylacetic acid derivatives. Sou...Scheme 2.12 Rh‐catalyzed meta‐C–H olefination of phenylacetic acid der...Scheme 2.13 Pyridine‐based template assisted meta‐C–H olefination of p...Scheme 2.14 (a) meta‐C‐H perfluoroalkenylation of phenylacetic acid derivati...Scheme 2.15 Pyridine‐based template assisted meta‐C–H arylation and io...Scheme 2.16 (a) meta‐C–H deuteration of phenylacetic acid derivatives

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