Non-equilibrium Thermodynamics of Heterogeneous Systems. Signe KjelstrupЧитать онлайн книгу.
entropy production for the surface
5.1The discrete nature of the surface
5.2The behavior of the electric fields and the potential through the surface
5.4The excess entropy production
5.4.1Reversible processes at the interface and the Nernst equation
5.4.2The surface potential jump at the hydrogen electrode
6The excess entropy production for a three-phase contact line
6.1The discrete nature of the contact line
6.3The excess entropy production
7Flux equations and Onsager relations
7.2Onsager’s reciprocal relations
7.3Relaxation to equilibrium: Consequences of violating Onsager relations
7.6The Curie principle applied to surfaces and contact lines
8.2Coefficient values for homogeneous phases
8.3.1Heats of transfer for the surface
8.4Solution for the heterogeneous system
8.5Scaling relations between surface and bulk resistivities
9.5Solution for the heterogeneous system
10Transport of mass and charge
10.3Solution for the heterogeneous system
10.5Electric power from volume flow
10.6Ionic mobility model for the electrolyte
10.7Ionic and electronic model for the surface
11Evaporation and condensation
11.1Evaporation and condensation in a pure fluid
11.1.1The entropy production and the flux equations
11.1.2Interface resistivities from kinetic theory
11.2The sign of the heats of transfer of the surface
11.3Coefficients from molecular dynamics simulations
11.4Evaporation and condensation in a two-component fluid
11.4.1The entropy production and the flux equations
11.4.2Interface resistivities from kinetic theory
12Multi-component diffusion, heat conduction and cross effects
12.2The Maxwell–Stefan equations for multi-component diffusion
12.3The Maxwell–Stefan equations for the surface