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      1  Cover

      2  Title Page

      3  Copyright

      4  1 Introduction: A Delicate Collection of Advances in Solar‐to‐Chemical Conversions Hongqi Sun

      5  2 Artificial Photosynthesis and Solar Fuels Jun Ke 2.1 Introduction of Solar Fuels 2.2 Photosynthesis 2.3 Principles of Photocatalysis 2.4 Products of Artificial Photosynthesis 2.5 Perspective Acknowledgments References

      6  3 Natural and Artificial Photosynthesis Dimitrios A. Pantazis 3.1 Introduction 3.2 Overview of Natural Photosynthesis 3.3 Light Harvesting and Excitation Energy Transfer 3.4 Charge Separation and Electron Transfer 3.5 Water Oxidation 3.6 Carbon Fixation 3.7 Conclusions References

      7  4 Photocatalytic Hydrogen Evolution Amanj Kheradmand, Yuxiang Zhu, Shengshen Gu and Yijiao Jiang 4.1 Introduction 4.2 Fundamentals of Photocatalytic H2 Evolution 4.3 Photocatalytic H2 Evolution Under UV Light 4.4 Photocatalytic H2 Evolution Under Visible Light 4.5 Photocatalytic H2 Evolution Under Near‐Infrared Light 4.6 Roles of Sacrificial Reagents and Reaction Pathways 4.7 Summary and Outlook References

      8  5 Photoelectrochemical Hydrogen Evolution Zhiliang Wang and Lianzhou Wang 5.1 Background of Photoelectrocatalytic Water Splitting 5.2 Mechanism of Charge Separation and Transfer 5.3 Strategy for Improving Charge Transfer 5.4 Strategy for Improving Electron–Hole Separation 5.5 Surface Cocatalyst Design 5.6 Unbiased PEC Water Splitting 5.7 Conclusion and Perspective References

      9  6 Photocatalytic Oxygen Evolution Huayang Zhang, Wenjie Tian and Shaobin Wang 6.1 Introduction 6.2 Homogeneous Photocatalytic Water Oxidation 6.3 Heterogeneous Photocatalytic Water Oxidation 6.4 Catalytic Active Site–Catalysis Correlation in LD Semiconductors 6.5 Conclusions and Perspectives References

      10  7 Photoelectrochemical Oxygen Evolution Fumiaki Amano 7.1 Introduction 7.2 Honda–Fujishima Effect 7.3 Factors Affecting the Photoanodic Current 7.4 Electrode Potentials at Different pH 7.5 Evaluation of PEC Performance 7.6 Flat Band Potential and Photocurrent Onset Potential 7.7 Selection of Materials 7.8 Enhancement of PEC Properties 7.9 PEC Device for Water Splitting 7.10 Conclusions and Outlook References

      11  8 Photocatalytic and Photoelectrochemical Overall Water Splitting Nur Aqlili Riana Che Mohamad, Filipe Marques Mota and Dong Ha Kim 8.1 Introduction 8.2 Photocatalytic Overall Water Splitting 8.3 Photoelectrochemical Overall Water Splitting 8.4 Concluding Remarks and Outlook Acknowledgments References

      12  9 Photocatalytic CO₂ Reduction Maochang Liu, Guijun Chen, Boya Min, Jinwen Shi, Yubin Chen